Does Water Prefer to Donate a Proton to AN F or to a cl Atom? - a Rotational Study of CH3CHClF...H2O

Details Does Water Prefer to Donate a Proton to AN F or to a cl Atom? - a Rotational Study of CH3CHClF...H2O Does Water Prefer to Donate a Proton to AN F or to a cl Atom? - a Rotational Study of CH3CHClF...H2O

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confemh04f&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

Physics

Microwave

Scientific paper

We measured the molecular beam Fourier transform microwave spectra of six isotopologues of the 1:1 adduct of CH3CHClF with water. The water prefers to form an O-H...F rather than an O-H...Cl hydrogen bond. This is exactly the contrary of what observed in the chlorofluoromethane-water adduct, where a O-H...Cl link was formed. Besides the rotational constants, the quadrupole coupling constants of the chlorine atom have been determined. In addition, information on the internal dynamics has been obtained.
W.Caminati, S.Melandri, A.Maris and P.Ottaviani, Angew. Chem. Int. Ed. 45, 2438-2442 (2006).

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