Dissociation constants of KSO 4 - from 10°-50°C

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A cell without liquid junction was used to obtain dissociation constants for the reaction: KSO 4 - = K + + SO 4 2- . At 10°, 25°, 38° and 50°C, values for K diss KSO 4 - are, respectively, 0.19 5 , 0.14 2 , 0.11 7 , and 0.09 5 . At 25°C, G f , and H f ° values for the KSO 4 - ion are -245.96 and -274.02 kcal mole -1 , and S ° is +42.3 cal mole -1 deg -1 .

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