Physics – Chemical Physics
Scientific paper
2000-08-10
Physics
Chemical Physics
4 pages, 3 figures
Scientific paper
10.1088/0953-8984/13/13/102
Using computer simulations of two charged colloidal spheres with their counterions in a hard sphere solvent, we show that the granular nature of the solvent significantly influences the effective colloidal interaction. For divalent counterions, the total effective force can become attractive generated by counterion hydration, while for monovalent counterions the forces are repulsive and well-described by a solvent-induced colloidal charge renormalization. Both effects are not contained in the traditional "primitive" approaches but can be accounted for in a solvent-averaged primitive model.
Allahyarov Elshad
L{ö}wen H.
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