Dipole moments and transition probabilities of the a 3Sigma(+)g - b 3Sigma(+)u system of molecular hydrogen

Details Dipole moments and transition probabilities of the a 3Sigma(+)g - b 3Sigma(+)u system of molecular hydrogen Dipole moments and transition probabilities of the a 3Sigma(+)g - b 3Sigma(+)u system of molecular hydrogen

Sep 1986

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1986phrva..34.1962k&link_type=abstract

Physical Review A - General Physics, 3rd Series (ISSN 0556-2791), vol. 34, Sept. 1986, p. 1962-1965.

Physics

General Physics

20

Dipole Moments, Hydrogen, Molecular Spectra, Transition Probabilities, Emission Spectra, Radiative Lifetime, Spontaneous Emission, Stellar Atmospheres, Wave Functions

Scientific paper

Multiconfiguration variational calculations of the electronic wave functions of the a 3Sigma(+)g and b 3Sigma(+)u states of molecular hydrogen are presented, and the electric dipole transition moment between them (of interest in connection with stellar atmospheres and the UV spectrum of the Jovian planets) is obtained. The dipole moment is used to calculate the probabilities of radiative transitions from the discrete vibrational levels of the a 3Sigma(+)g state to the vibrational continuum of the repulsive b 3Sigma(+)u state as functions of the wavelength of the emitted photons. The total transition probabilities and radiative lifetimes of the levels v prime = 0-20 are presented.

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