Diode-laser measurements of N2-broadening coefficients in the ν2 band of HCN

Details Diode-laser measurements of N2-broadening coefficients in the ν2 band of HCN Diode-laser measurements of N2-broadening coefficients in the ν2 band of HCN

Feb 1992

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992jmosp.151..292s&link_type=abstract

Journal of Molecular Spectroscopy, Volume 151, Issue 2, p. 292-302.

Physics

11

Scientific paper

N2-broadening coefficients have been measured for 41 lines (with J values ranging from 2 to 33) of HCN in the P, Q, and R branches of the ν2 band. These lines, located in the spectral range 610-810 cm-1, were recorded with a high-resolution tunable diode-laser spectrometer. A semiclassical impact calculation of these collisional broadenings provides results in the P and R branches as well as in the Q branch that for J > 10 are generally larger than the experimental data.
Laboratoire associé aux Universités Paris-Sud et Pierre et Marie Curie.

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