Development of a configuration-interaction + all-order method for atomic calculations

Details Development of a configuration-interaction + all-order method for atomic calculations Development of a configuration-interaction + all-order method for atomic calculations

2009-05-15

arxiv.org/abs/0905.2578v1

Phys. Rev. A 80, 012516 (2009)

Physics

Atomic Physics

10 pages

Scientific paper

10.1103/PhysRevA.80.012516

We develop a theoretical method within the framework of relativistic many-body theory to accurately treat correlation corrections in atoms with few valence electrons. This method combines the all-order approach currently used in precision calculations of properties of monovalent atoms with the configuration-interaction approach that is applicable for many-electron systems. The method is applied to Mg, Ca, Sr, Zn, Cd, Ba, and Hg to evaluate ionization energies and low-lying energy levels.

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