Detection of the nonlinear behavior of the H2O vibrational-rotational line shift by H2 pressure

Details Detection of the nonlinear behavior of the H2O vibrational-rotational line shift by H2 pressure Detection of the nonlinear behavior of the H2O vibrational-rotational line shift by H2 pressure

Nov 1991

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1991opat....4.1143l&link_type=abstract

Optika Atmosfery (ISSN 0235-277X), vol. 4, no. 11, Nov. 1991, p. 1143-1146. In Russian.

Physics

Optics

Gas Pressure, Hydrogen, Line Spectra, Rotational Spectra, Vibrational Spectra, Water, Absorption Spectra, Atmospheric Optics, Molecular Gases, Partial Pressure, Planetary Atmospheres

Scientific paper

The H2 pressure broadening and shift coefficients have been measured for H2O absorption line at 694.38 nm corresponding to the transition 4(14)-5(15) of the 000-103 band. Experimental results indicate that the pressure behavior of the H2O absorption line center shift deviates from the linear one at H2 pressure above 450 to 500 torr. This has not previously been observed for any mixture of H2O vapor with atomic (Ne, Ar, Kr, and Xe) or molecular (N2, O2 and air) gases.

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