Detection of carbonyl fluoride in the stratosphere

Physics

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Atmospheric Composition, Carbonyl Compounds, Fluorides, Solar Spectra, Stratosphere, Absorption Spectra, Michelson Interferometers, Spaceborne Experiments, Spacelab Payloads, Spectral Bands

Scientific paper

Infrared solar absorption spectra of the stratosphere recorded at a resolution of 0.01/cm by the ATMOS (Atmospheric Trace Molecule Spectroscopy) instrument from onboard Spacelab 3 (04/30 to 05/6/85) have revealed the existence of many previously unobserved absorption features in the 1925 to 1960/cm and 1249 to 1255/cm regions and one at 774/cm. On the basis of comparisons with laboratory spectra, these features have been identified as belonging to the nu1, nu4, and nu6 bands of carbonyl fluoride, respectively. Volume mixing ratios of COF2 between 17 and 40 km have been deduced from analysis of the nu1 and nu6 bands.

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