Detailed kinetic models for the low-temperature auto ignition of gasoline surrogates

Details Detailed kinetic models for the low-temperature auto ignition of gasoline surrogates Detailed kinetic models for the low-temperature auto ignition of gasoline surrogates

2009-04-20

arxiv.org/abs/0904.2967v1

Physics

Chemical Physics

European Combustion Meeting 2009 (ECM 2009), Vienne : Autriche (2009)

Scientific paper

In the context of the search for gasoline surrogates for kinetic modeling purpose, this paper describes a new model for the low-temperature auto-ignition of n-heptane/iso-octane/hexene/toluene blends for the different linear isomers of hexene. The model simulates satisfactory experimental results obtained in a rapid compression machine for temperatures ranging from 650 to 850 K in the case of binary and ternary mixtures including iso octane, 1-hexene and toluene. Predictive simulations have also been performed for the autoignition of n heptane/iso octane/hexene/toluene quaternary mixtures: the predicted reactivity is close to that of pure iso octane with a retarding effect when going from 1- to 3-alkene.

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