Correlation between the energy shell structure and geometry in metallic nanoclusters: quasi-resonance states, isotope effect

Physics – Atomic and Molecular Clusters

Scientific paper

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Scientific paper

10.1063/1.2841469

Metallic nanoclusters displaying electronic shell structure exhibit the special feature of a correlation between their geometry and the number of delocalized electrons . Their shape evolution can be described as a quantum oscillation between quasi-resonant states (prolate and oblate configurations) whose amplitudes depend upon the degree of shell filling. The picture explains the evolution of absorption spectra and predicts a peculiar isotope effect .

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