Physics – Chemical Physics
Scientific paper
2012-03-27
Physics
Chemical Physics
11 pages, 9 figures
Scientific paper
We study how the combination of long and short laser pulses, can be used to induce torsion in an axially chiral biphenyl derivative (3,5-difluoro-3',5'-dibromo-4'-cyanobiphenyl). A long, with respect to the molecular rotational periods, elliptically polarized laser pulse produces 3D alignment of the molecules, and a linearly polarized short pulse initiates torsion about the stereogenic axis. The torsional motion is monitored in real-time by measuring the dihedral angle using femtosecond time-resolved Coulomb explosion imaging. Within the first 4 picoseconds, torsion occurs with a period of 1.25 picoseconds and an amplitude of 3 degrees in excellent agreement with theoretical calculations. At larger times the quantum states of the molecules describing the torsional motion dephase and an almost isotropic distribution of the dihedral angle is measured. We demonstrate an original application of covariance analysis of two-dimensional ion images to reveal strong correlations between specific ejected ionic fragments from Coulomb explosion. This technique strengthens our interpretation of the experimental data.
Hansen Jonas L.
Johansson Mikael P.
Lindhardt Anders Thyboe
Madsen Christian Bruun
Madsen Lars Bojer
No associations
LandOfFree
Control and femtosecond time-resolved imaging of torsion in a chiral molecule does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Control and femtosecond time-resolved imaging of torsion in a chiral molecule, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Control and femtosecond time-resolved imaging of torsion in a chiral molecule will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-641118