Physics – Chemical Physics
Scientific paper
2009-09-28
Physics
Chemical Physics
This manuscript is a significant rewrite of an earlier manuscript (arXiv:0906.3914). The current version expands significantly
Scientific paper
We propose a minimal model Hamiltonian for the electronic structure of a monomethine dye, in order to describe the photoisomerization of such dyes. The model describes interactions between three diabatic electronic states, each of which can be associated with a valence bond structure. Monomethine dyes are characterized by a charge-transfer resonance; the indeterminacy of the single-double bonding structure dictated by the resonance is reflected in a duality of photoisomerization pathways corresponding to the different methine bonds. The possible multiplicity of decay channels complicates mechanistic models of the effect of the environment on fluorescent quantum yields, as well as coherent control strategies. We examine the extent and topology of intersection seams between the electronic states of the dye, and how they relate to charge localization and selection between different decay pathways. We find that intersections between the S1 and S0 surfaces only occur for large twist angles. In contrast, S2/S1 intersections can occur near the Franck-Condon region. When the molecule has left-right symmetry, all intersections are associated with con- or dis-rotations and never with single bond twists. For asymmetric molecules (i.e. where the bridge couples more strongly to one end) then the S2 and S1 surfaces bias torsion about different bonds. Charge localization and torsion pathway biasing are correlated. We relate our observations to several recent experimental and theoretical results, which have been obtained for dyes with similar structure.
McKenzie Ross H.
Olsen Seth
No associations
LandOfFree
Conical Intersections, Charge Transfer and Photoisomerization Pathway Selection in a Minimal Model of a Degenerate Monomethine Dye does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Conical Intersections, Charge Transfer and Photoisomerization Pathway Selection in a Minimal Model of a Degenerate Monomethine Dye, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Conical Intersections, Charge Transfer and Photoisomerization Pathway Selection in a Minimal Model of a Degenerate Monomethine Dye will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-664372