Physics – Atomic Physics
Scientific paper
2004-09-08
Physics
Atomic Physics
6 pages, REVTeX4 style, submitted to Pthys.Rev.A
Scientific paper
10.1103/PhysRevA.72.022505
We report first configuration interaction calculations of hyperfine constants A_\parallel and the effective electric field W_d acting on the electric dipole moment of the electron, in two excited electronic states of ^{207}PbO. The obtained hyperfine constants, A_\parallel = -3826 MHz for the a(1) state and A_\parallel = 4887 MHz for the B(1) state, are in very good agreement with the experimental data, -4113 MHz and 5000 \pm 200 MHz, respectively. We find W_d = -(6.1 ^{+1.8}_{-0.6}) 10^{24} Hz/(e cm) for a(1), and W_d = (8.0 \pm 1.6) 10^{24} Hz/(e cm) for B(1). The obtained values are analyzed and compared to recent relativistic coupled cluster results and a semiempirical estimate of W_d for the a(1) state.
DeMille David
Isaev T. A.
Mosyagin Nikolai S.
Petrov Alexander N.
Titov Anatoly V.
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