Complex molecules in cesium-rare earth iodide vapors

Details Complex molecules in cesium-rare earth iodide vapors Complex molecules in cesium-rare earth iodide vapors

Mar 1974

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1974jchph..60.2384l&link_type=abstract

Journal of Chemical Physics, Volume 60, Issue 6, pp. 2384-2390 (1974).

Physics

Chemical Physics

6

Scientific paper

The optical absorption of the vapors above neodymium iodide and cerium iodide were studied: (1) individually, (2) in combination with cesium iodide, and (3) in combination with cesium iodide and mercury between 600 and 1100°C. Changes in the spectra show that a stable complex molecule CsI . NdI3 is formed that increases the amount of Nd vaporized. A similar enhancement of the vaporization of Ce appears to occur with the cerium plus cesium iodide system, but no changes in absorption structure were found. At high mercury pressure a weak complex between Hg and CsI . NdI3 apparently forms. Vapor pressures and thermodynamic quantities have been deduced from the data.

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