Collisional excitation of water in warm media (Faure+, 2008)

Physics – Atomic Physics

Scientific paper

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Atomic Physics

Scientific paper

*Downward* pure rotational and ro-vibrational rates are provided for the 5 lowest vibrational levels of H2O and 11 temperatures (from 200 to 5000K). This corresponds to all possible transitions among the lowest 824th levels of H2O below 5000cm-1. Upward rates can be computed using the detailed balance relation (see article).
Rate files are denoted as
p-h2o-h2-vi-vf.dat and o-h2o-h2-vi-vf.dat
for para-H20 and ortho-H20 colliding with H2, respectively, and
p-h2o-e-vi-vf.dat or o-h2o-e-vi-vf.dat
for para-H20 and ortho-H20 colliding with electrons, respectively.
The notation 'vi-vf' corresponds to transitions from an initial vibrational state vi to a final vibrational state vf. The standard notation v1v2v3, e.g vi=010 and vf=000, is employed. It represents vibrational quanta in normal modes v1 (symmetric stretch), v2 (bending) and v3 (antisymmetric stretch), respectively.
The labelling of para- and ortho-H2O levels in rate files correspond to the labelling in files p-h2o.xxx.levels and o-h2o.xxx.levels where 'xxx' is a vibrational level, e.g. 010.
(3 data files).

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