Physics
Scientific paper
Oct 2009
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009phrva..80d2703k&link_type=abstract
Physical Review A, vol. 80, Issue 4, id. 042703
Physics
2
Interatomic And Intermolecular Potentials And Forces, Potential Energy Surfaces For Collisions, Calculations And Mathematical Techniques In Atomic And Molecular Physics, Infrared Spectra, Atomic And Molecular Data, Spectra, And Spectral Parameters
Scientific paper
The diagrammatic theory, developed recently by the authors [Phys. Rev. A 74, 012732 (2006)], is applied to binary collision-induced properties, with emphasis on induced dipole moments. Assuming rototranslational dynamics to be classical and using irreducible spherical tensor formalism, exact analytical formulas are worked out for the two leading order spectral moments of a collision-induced band by two interacting linear molecules. The formulas are applied to the far infrared absorption by CO2-CO2 , and permit interpretation of the experiment. This study provides evidence of the adequacy of the electrostatic induction mechanism, provided that hitherto missing vibrational terms of static polarizability are considered.
Chrysos M.
Kouzov A. P.
No associations
LandOfFree
Collision-induced absorption by CO2 in the far infrared: Analysis of leading-order moments and interpretation of the experiment does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Collision-induced absorption by CO2 in the far infrared: Analysis of leading-order moments and interpretation of the experiment, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Collision-induced absorption by CO2 in the far infrared: Analysis of leading-order moments and interpretation of the experiment will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-1428267