Collective plasmonic modes of metal nano-particles in two-dimensional periodic regular arrays

Physics – Optics

Scientific paper

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26 pages, 8 figures

Scientific paper

10.1103/PhysRevB.78.035419

We investigate the collective plasmonic modes of metal nano-particles in periodic two-dimensional (2D) arrays within a point-dipole description. As an open system, the full-dynamic dispersion relations of the 2D arrays are obtained through an efficient method which gives an effective polarizability describing the collective response of a system. Both the dispersion relations and mode qualities are simultaneously related to the imaginary part of the effective polarizability, which has contributions from the single-particle response as well as the inter-particle coupling. The transversal long-range dipolar interaction is dominated by a wave term together with a purely geometrical constant representing the static geometrical contribution to resonant frequencies. As concrete examples, we considered small Ag spheres arranged in a square lattice. We find that inside the light-cone, the transverse quasi-mode has a reasonably high mode quality while the two in-plane modes show significant radiation damping. Near the light-line, we observe strong coupling with free photons for the bands of the transverse mode and the transversal in-plane mode, and the longitudinal in-plane mode exhibits a negative group-velocity inside the light-cone. Vanishing group velocities in the light-cone for all the quasi-modes are found to be intrinsic properties of the 2D metal nano-sphere dense arrays.

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