CO vibrational stimulated emission in a Hg-CO-N2 matrix

Physics – Optics

Scientific paper

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Carbon Monoxide, Gas Mixtures, Infrared Lasers, Stimulated Emission, Ultrashort Pulsed Lasers, Vibrational Spectra, Additives, Krypton Fluoride Lasers, Mercury (Metal), Nitrogen, Time Response

Scientific paper

Infrared stimulated emission on the v equals 5 to 4 transition of CO was observed in a mercury doped CO-N2 low temperature matrix irradiated with a KrF excimer laser. It consists of a 20-50 ns pulse at 2032/cm occurring at not less than 17 K and for a pump energy of greater than 0.5 J/sq cm. A theoretical model predicts that the observed emission is composed of short peaks separated by less than 2 ns. They are unresolved in the experiment because of the low time resolution of the signal acquisition device.

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