Clustering reactions of H2CN(+) ions with HCN

Details Clustering reactions of H2CN(+) ions with HCN Clustering reactions of H2CN(+) ions with HCN

Aug 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987jchph..87.2399c&link_type=abstract

Journal of Chemical Physics (ISSN 0021-9606), vol. 87, Aug. 15, 1987, p. 2399, 2400.

Physics

Chemical Physics

4

Hydrocyanic Acid, Molecular Ions, Reaction Kinetics, Association Reactions, Gas Temperature, Helium, Positive Ions

Scientific paper

The rate coefficients for the first and second steps in the clustering sequence of H2CN(+) ions with HCN, H2CN(+) + HCN + M - H2CN(+) (HCN) + M and H2CN(+) (HCN) + HCN + M - H2CN(+) (HCN)2 + M, have been measured at temperatures from 189 to 296 K for M = He. The three-body association rate coefficients for both reactions are least-squares fitted for a power dependence on gas temperature. The temperature dependences of the three-body association reaction rate coefficients fitted in the range 200 to 300 K are given. The absolute values and temperature dependences are rather similar.

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