Physics
Scientific paper
Sep 1994
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1994georl..21.2043d&link_type=abstract
Geophysical Research Letters (ISSN 0094-8276), vol. 21, no. 18, p. 2043-2046
Physics
37
Chemical Reactions, Dayglow, Electric Potential, Nitric Oxide, Nitrogen, Oxygen, Thermosphere, Energy Distribution, Rotational Spectra, Temperature Effects, Vibrational Spectra
Scientific paper
Classical trajectory calculations have been performed to determine the reaction rate constants and NO final vibrational-rotational distributions of the N((4)S) + O2 reaction at hyperthermal translational energies. The reaction occurs on two electronic potential energy surfaces, both of which must be considered for a realistic description of the N((4)S) + O2 dynamics. The calculations, which are in good agreement with the available experimental data, show that the reaction has a very strong translational energy dependence and produces NO with extensive vibrational and rotational excitation. The present study provides the N((4)S) + O2 reaction attributes necessary to predict NO formation and emission from translationally hot N((4)S) in the thermosphere.
Bien Fritz
Duff James W.
Paulsen Duane E.
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