Classical dynamics of the N((4)S) + O2(X(3)Σ g- yields NO(X(2)Pi) + O((3)P)

Physics

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Chemical Reactions, Dayglow, Electric Potential, Nitric Oxide, Nitrogen, Oxygen, Thermosphere, Energy Distribution, Rotational Spectra, Temperature Effects, Vibrational Spectra

Scientific paper

Classical trajectory calculations have been performed to determine the reaction rate constants and NO final vibrational-rotational distributions of the N((4)S) + O2 reaction at hyperthermal translational energies. The reaction occurs on two electronic potential energy surfaces, both of which must be considered for a realistic description of the N((4)S) + O2 dynamics. The calculations, which are in good agreement with the available experimental data, show that the reaction has a very strong translational energy dependence and produces NO with extensive vibrational and rotational excitation. The present study provides the N((4)S) + O2 reaction attributes necessary to predict NO formation and emission from translationally hot N((4)S) in the thermosphere.

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