Chromium-aluminum mixing in garnet: A thermochemical study

Details Chromium-aluminum mixing in garnet: A thermochemical study Chromium-aluminum mixing in garnet: A thermochemical study

Jun 1984

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1984gecoa..48.1373w&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 48, Issue 6, pp.1373-1375

Physics

3

Scientific paper

The enthalpies of mixing of synthetic grossular (Ca 3 Al 2 Si 3 O 12 )-uvarovite (Ca 3 Cr 2 Si 3 O 12 ) solid solutions have been determined by oxide melt calorimetry at 970 K. The results indicate that the solid solution exhibits a very small negative deviation from Raoult's law. In terms of the regular solution model a chromium-aluminum interaction parameter W H Cr - Al of between 0 and -1000 cal/gm atom is consistent with the data.

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