Chiral Interactions of Histidine in a Hydrated Vermiculite

Physics – Biological Physics

Scientific paper

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10 Pages, 5 Figures

Scientific paper

Recent work suggests a link between chiral asymmetry in the amino acid iso-valine extracted from the Murchison meteorite and the extent of hydrous alteration. We present the results of neutron scattering experiments on an exchanged, 1-dimensionally ordered n-propyl ammonium vermiculite clay. The vermiculite gel has a (001) d-spacing of order 5nm at the temperature and concentration of the experiments and the d-spacing responds sensitively to changes in concentration, temperature and electronic environment. The data show that isothermal addition of D-histidine or L-histidine solutions produces shifts in the d-spacing that are different for each enantiomer. This chiral specificity is of interest for the question of whether clays could have played an important role in the origin of biohomochirality.

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