Charge transfer between ground-state N2+ and H2, N2, and CO at electron-volt energies

Details Charge transfer between ground-state N2+ and H2, N2, and CO at electron-volt energies Charge transfer between ground-state N2+ and H2, N2, and CO at electron-volt energies

Jan 1997

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1997phrva..55..440f&link_type=abstract

Physical Review A (Atomic, Molecular, and Optical Physics), Volume 55, Issue 1, January 1997, pp.440-443

Physics

8

Scientific paper

The charge-transfer rate coefficients for reactions of N2+(2s22p 2Po) with H2, N2, and CO are measured using ion storage. A cylindrical rf ion trap was used to store N2+ ions produced by laser ablation of a solid titanium nitride target. The rate coefficients were derived from the decay rate of the ion signal. The rate coefficients for the above three reactions are 3.38(0.35)×10-11 cm3 s-1 at Tequiv=2.9×103 K, 2.10(0.18)×10-9 cm3 s-1 at Tequiv=1.3×104 K, and 3.37(0.29)×10-9 cm3 s-1 at Tequiv=1.3×104 K, respectively. No theoretical or other experimental values are available at this energy range.

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