Carbon-13 fractionation between aragonite and calcite

Details Carbon-13 fractionation between aragonite and calcite Carbon-13 fractionation between aragonite and calcite

Aug 1969

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1969gecoa..33..997r&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 33, Issue 8, pp.997-1002

Physics

21

Scientific paper

Aragonite and calcite were precipitated from bicarbonate solutions by slow removal of carbon dioxide at 25°C. Carbon isotope fractionation factors (expressed as 1000 ln ) are: calcite-bicarbonate ion 0.9 ± 0.2; aragonite-bicarbonate ion 2.7 ± 0.2; aragonite-calcite 1.8 ± 0.2. Theoretical calculation of the aragonite-calcite fractionation gives 0.9.

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