Calculated line positions and intensities for the nu1 plus nu3 and nu1 plus nu2 plus nu3 minus nu2 bands of N/14//O-16/2

Physics

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Ground State, Molecular Spectra, Nitrogen Dioxide, Spectral Bands, Spectral Energy Distribution, Coriolis Effect, Hamiltonian Functions, Infrared Spectra, Least Squares Method, Line Spectra, Molecular Rotation

Scientific paper

An improved set of line positions and intensities for the nu1 plus nu3 and nu1 plus nu2 plus nu3 minus nu2 bands of NO2 absorbing in the 3.4 micron region are generated. The calculations include the effect of the Coriolis resonance both on the energy levels and the wave functions and on the line intensities. A number of 6860 lines having an intensity larger than 0.2 x 10 to the minus 23rd per cm per molecule-sq cm have been computed and the total band intensity of the nu1 plus nu3 and nu1 plus nu2 plus nu3 minus nu2 bands at 296 K are respectively 0.288 x 10 to the minus 17th and 0.107 x 10 to the minus 18th per cm per molecule-sq cm.

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