Calculated helium-broadened line parameters in the ν4 band of 13CH4.

Physics

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Methane: Line Broadening, Methane: Laboratory Spectra, Methane: Planetary Atmospheres

Scientific paper

Helium line-broadening coefficients for transitions in the ν4 band of 13CH4 have been calculated using a semi-classical model. This model is analogous to the one that the author has used in a previous study on argon line-broadening coefficients for transitions in the ν3 band of 12CH4. For the present study, over 270 room temperature measurements were considered. The J, symmetry and fine structure dependences of the data are satisfactorily reproduced, although deficiencies of the semi-classical model are evidenced.

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