C, N, O isotope fractionation on Mars - Implications for crustal H2O and SNC meteorites

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Achondrites, Carbon Isotopes, Chemical Fractionation, Mars (Planet), Nitrogen Isotopes, Oxygen Isotopes, Carbon 12, Carbon 13, Mars Atmosphere, Nitrogen 15, Oxygen 18, Water, Meteorites, Mars, Isotopes, Fractionation, Crust, Water, Snc Meteorites, Carbon, Nitrogen, Oxygen, Nitrogen 15, Enrichment, Outgassing, Atmosphere, Theoretical Studies

Scientific paper

Data on C, N, and O inclusions on Mars are examined in order to investigate the historical atmosphere of the planet. The results indicate a ratio of N-15:N-14 escape rates of 0.53-0.62, suggesting a lower than 1 mb initial complement of nitrogen. Alternately, the low enrichment of N-15 observed by Viking may result from continuous outgassing from the surface together with the current loss processes, a scenario which is consistent with an initial complement of N2 lost via physical or chemical processes early in the planet's evolution. It is suggested that abundant kilometer-deep H2O has persisted up to the present epoch, and that the Martian atmosphere as occluded in SNC meteorites during the last 1.3 Ga would be a little lighter isotopically in C and O, but potentially heavier in N, than the current atmosphere.

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