Breakdown of Angular Momentum Selection Rules in High Pressure Optical Pumping Experiments

Physics – Atomic Physics

Scientific paper

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Scientific paper

We present measurements, using two complementary methods, of the breakdown of
atomic angular momentum selection rules in He-broadened Rb vapor. Atomic dark
states are rendered weakly absorbing due to fine-structure mixing during Rb-He
collisions. The effect substantially increases the photon demand for optical
pumping of dense vapors.

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