Band oscillator strengths of the (2, 1)-(12, 1) Schumann-Runge bands of O2 from absolute absorption cross-section measurements at room temperature

Details Band oscillator strengths of the (2, 1)-(12, 1) Schumann-Runge bands of O2 from absolute absorption cross-section measurements at room temperature Band oscillator strengths of the (2, 1)-(12, 1) Schumann-Runge bands of O2 from absolute absorption cross-section measurements at room temperature

Jul 1990

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1990jgr....9511743y&link_type=abstract

Journal of Geophysical Research (ISSN 0148-0227), vol. 95, July 20, 1990, p. 11743-11746.

Physics

9

Absorption Cross Sections, Earth Atmosphere, Oscillator Strengths, Oxygen Spectra, Schumann-Runge Bands, Atmospheric Radiation, Electron Transitions, Molecular Energy Levels, Room Temperature, Rotational Spectra, Vibrational Spectra

Scientific paper

The absolute absorption cross section of the (2, 1)-(12, 1) Schumann-Runge bands of O2 at room temperature have been obtained from measurements of the total absolute absorption cross sections arising from transitions from the ground-state levels with v-double prime = 0 and 1 by subtraction of the v-double prime = 0 contributions, which have been synthesized from previous determinations of the band oscillator strengths, line center positions, and predissociation line widths of the (v-prime, 0) Schumann-Runge bands of O2. The resultant absolute absorption cross sections of the (2, 1)-(12, 1) bands have been integrated numerically to obtain the band oscillator strengths. The experimental band oscillator strengths are somewhat lower than the experimental values of Lewis et al. (1986) but are in good agreement with the recently calculated values of Friedman (1990).

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