Atmospheric transmittance and photodissociation rates in the 185-240 nm specral range - Sensitivity of O2 absorption cross sections in the Herzberg continuum and Schumann Runge bands

Physics – Optics

Scientific paper

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Atmospheric Optics, Herzberg Bands, Oxygen Spectra, Photodissociation, Schumann-Runge Bands, Transmittance, Absorption Spectra, Carbon Tetrachloride, Molecular Gases, Nitrous Oxides, Reaction Kinetics, Spectral Energy Distribution, Stratosphere, Ultraviolet Spectra

Scientific paper

Recent solar irradiation measurements at 30-40 km altitudes have indicated that absorption cross sections for molecular oxygen in the 200-210 nm Herzberg continuum have been overestimated by more than 30 percent. Attention is presently given to the requirement for accurate calculations of atmospheric transmittance, down to 190 nm, for the determination of stratospheric photodissociation rates; source species photodissociation data are examined for the cases of nitrous oxide and chlorine species.

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