Arsenous acid ionisation in aqueous solutions from 25 to 300 °C

Physics

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Scientific paper

The ultraviolet spectra of dilute, aqueous arsenic (III)-containing solutions have been measured from 25 to 300 °C at the saturated vapour pressure. From these measurements, the equilibrium constant was obtained for the reaction H3AsO3⇄H+H2AsO3-; for which pK1 (arsenous acid) decreases from 9.25 to 7.11 over a temperature range from 25 to 300 °C. In addition, electrospray mass spectrometric measurements support the conclusion that the arsenous acid moeities in low density aqueous media are HAsO2 and AsO2-.

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