Approximation for the vibrational excitation of middle atmospheric NO by upwelling radiation

Physics – Optics

Scientific paper

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Middle Atmosphere, Molecular Excitation, Nitric Oxide, Vibrational Spectra, Atmospheric Composition, Atmospheric Models, Mesosphere, Radiance, Remote Sensing, Stratosphere

Scientific paper

Results for upward and downward IR flux density and angle-averaged radiance obtained using a plane-parallel approximation are compared with data that account for planetary curvature. It is found that upwelling radiation typically contributes less than about 2.5 percent to the total NO(v = 1) excitation in the midstratosphere, rises to about 5 percent at 50 km, and becomes increasingly significant at higher altitudes. In the mesosphere, excitation due to upwelling and solar radiation becomes important with respect to the dominant processes of thermal collisions and chemical excitation.

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