Application of Two-Step Laser Mass Spectrometry to Cosmogeochemistry: Direct Analysis of Meteorites

Physics

Scientific paper

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Scientific paper

Polycyclic aromatic hydrocarbons in C1, C2, and C3 carbonaceous chondrites and in some ordinary chondrites have been directly analyzed by two-step laser desorption/laser multiphoton ionization mass spectrometry, a selective and sensitive method requiring only milligram samples. At the ionization wavelength of 266 nanometers, parent ion peaks of polycyclic aromatic hydrocarbons dominate the mass spectra. Quantitative analysis is possible; as an example, the concentration of phenanthrene in the Murchison meteorite was determined to be 5.0 parts per million.

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