Application of a ΔE-E telescope for sensitive ERDA measurement of hydrogen

Physics

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Elastic Recoil Detection, Erda, Hydrogen, Silicates, Diamonds

Scientific paper

A ΔE-E telescope was used in coincidence to separate the isotopes of hydrogen and to improve the sensitivity of hydrogen detection when recoiled with 3.8MeV He+. This was achieved by recording coincident events in both detectors (corresponding to the recoil of H, D or T from the target) thereby excluding any contribution from D (or T) beam contamination to the ERDA spectrum for hydrogen and also eliminating electronic noise from the background. The analysis of standard hydrogen-bearing silicates (6-189wtppm H) suggested that the concentrations at the lower part of this range were resolvable. The lowest counts were accumulated on two fragments of colourless diamond and were <20% of the counts obtained for the standard bearing 6wtppm H. We suggest sensitivities of better than 0.0056wt% H2O (or 75at.ppm H in carbon-rich matrices) are achievable with relative precisions <20% in the range 0-400at.ppm H.

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