Anomalous pH-gradient in Ampholyte Solution

Details Anomalous pH-gradient in Ampholyte Solution Anomalous pH-gradient in Ampholyte Solution

2009-02-21

arxiv.org/abs/0902.3758v1

Physics

Chemical Physics

5 pages, 2 figures

Scientific paper

A mathematical model describing a steady pH-gradient in the solution of ampholytes in water has been studied with the use of analytical, asymptotic, and numerical methods. We show that at the large values of an electric current a concentration distribution takes the form of a piecewise constant function that is drastically different from a classical Gaussian form. The correspondent pH-gradient takes a stepwise form, instead of being a linear function. A discovered anomalous pH-gradient can crucially affect the understanding of an isoelectric focusing process.

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