Anion Chemistry on Titan: A possible route to large N-bearing hydrocarbons

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The CN- + HC3N reaction has been studied in a tandem mass spectrometer as a function of the HC3N target molecule going from a single to a multiple collision regime. The primary and secondary reactions with HC3N were found to be extremely efficient, resulting in anionic products of rapidly growing size through a simple mechanism [1]. Comparison of the experimental mass spectra with the spectrum observed on board of CASSINI with the CAPS-ELS instrument by Coates et al [2,3] suggests that the proposed mechanism may be of interest to describe the growth of negatively charged hydrocarbons in Titan's ionosphere [1].

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