Analysis of the A2Πi-X2Σ+ (comet-tail) system of the 14C16O+ molecule

Details Analysis of the A2Πi-X2Σ+ (comet-tail) system of the 14C16O+ molecule Analysis of the A2Πi-X2Σ+ (comet-tail) system of the 14C16O+ molecule

Sep 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987jmosp.125...43j&link_type=abstract

Journal of Molecular Spectroscopy, Volume 125, Issue 1, p. 43-53.

Physics

8

Scientific paper

Five bands (1-0, 2-0, 2-1, 3-0, and 4-0) of the A2Πi-X2Σ+ system of the 14C16O+ molecule have been photographed and analyzed for the first time. The 50 single-valued molecular constants of the A2Πi, v <= 4, X2Σ+, v = 0, 1, and B2Σ+, v = 0, 1 states reproducing the experimental wavenumbers within the accuracy of measurement have been obtained by using a multistep merging process. Finally, the rotational constants Be = 1.459378(41) and αe = 0.017092(16) and the vibrational constants ωe = 1497.013(13), ωexe = 12.509(7), and ωeye = 0.019(1) of the A2Πi state have been calculated. Perturbations in the 2-0 and 2-1 bands relevant to the interaction between the A2Πi, v = 2 and X2Σ+, v = 12 states have been detected.

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