Physics
Scientific paper
Apr 1998
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1998apphl..72.1781r&link_type=abstract
Applied Physics Letters, Volume 72, Issue 14, id. 1781 (1998).
Physics
53
Capacitors, Metal-Insulator-Metal Structures, Polymers, Organic Compounds, Permittivity
Scientific paper
Alkanethiol self-assembled monolayers (SAMs) on a mercury surface are used to build a junction consisting of two opposing mercury surfaces with interposed SAMs: Hg-SAM/SAM-Hg. The liquid mercury surface provides a support for the SAM that is smooth, compliant, free of defects, and without the incommensurate lattice properties that characterize solid metal surfaces. The thickness of the dielectric (~30-90 Å) in this junction can be easily changed by using alkanethiols with different lengths. From capacitance measurements, a dielectric constant of 2.7+/-0.3 is calculated for the SAMs. The conductivity of SAMs on the Hg surface is σ=6+/-2×10-15 Ω-1 cm-1, a value close to that of bulk polyethylene. The junction sustains an electric field of 6 MV/cm.
Rampi Maria A.
Schueller Olivier J. A.
Whitesides George M.
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