Algebraic approach to vibrational spectra of tetrahedral molecules: a case study of silicon tetrafluoride

Details Algebraic approach to vibrational spectra of tetrahedral molecules: a case study of silicon tetrafluoride Algebraic approach to vibrational spectra of tetrahedral molecules: a case study of silicon tetrafluoride

1998-01-11

arxiv.org/abs/physics/9801012v1

Physics

Chemical Physics

Revtex, 7 pages, no figure, to appear in Chem. Phys. Lett

Scientific paper

10.1016/S0009-2614(97)01357-2

Both the stretch and bend vibrational spectrum and the intensity of infrared
transitions in a tetrahedral molecule are studied in a U(2) algebraic model,
where the spurious states in the model Hamiltonian and the wavefunctions are
exactly removed. As an example, we apply the model to silicon tetrafluoride
SiF$_4$.

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