Air-broadened Lorentz halfwidths and pressure-induced line shifts in the nu(4) band of C-13H4

Physics – Optics

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19

Atmospheric Composition, Line Spectra, Lorentz Transformations, Methane, Fourier Transformation, Laser Spectroscopy, Least Squares Method, Spectrometers

Scientific paper

Air-broadened halfwidths and pressure-induced line shifts in the nu(4) fundamental of C-13H4 were determined from spectra recorded at room temperature and at 0.01/cm resolution using a Fourier transform spectrometer. Halfwidths and pressure shifts were determined for over 180 transitions belonging to J-double prime values of less than or = to 16. Comparisons of air-broadened halfwidths and pressure-induced line shifts made for identical transitions in the nu(4) bands of C-12H4 and C-13H4 have shown that C-13H4 air-broadened halfwidths are about 5 percent smaller than the corresponding C-12H4 halfwidths, and the pressure shifts for C-13H4 lines are about 5-15 percent larger than those for C-12H4.

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