Activation volume of silicon diffusion in San Carlos olivine

Physics

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Mineral Physics: Defects, Mineral Physics: High-Pressure Behavior, Physical Properties Of Rocks: Plasticity, Diffusion, And Creep, Physical Properties Of Rocks: Transport Properties

Scientific paper

The activation volume of silicon diffusion (VSi) in olivine is reported for the first time. Specimens of San Carlos olivine single crystal were annealed at 1763 K and at pressures to 9 GPa in an uniaxial split-sphere apparatus. 30Si was used as tracer and the diffusion profiles were analyzed using the resonant nuclear reaction 30Si(p,γ). We obtain VSi=(-1.9+/-2.4)×10-6m3/mol with a more probable value close to zero.

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