Physics
Scientific paper
Nov 1979
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1979georl...6..833d&link_type=abstract
Geophysical Research Letters, vol. 6, Nov. 1979, p. 833-836. U.S. Environmental Protection Agency
Physics
4
Actinometers, Atmospheric Chemistry, Oxygen Atoms, Ozone, Photolysis, Reaction Kinetics, Chemiluminescence, Nitrous Oxides, Radiation Effects, Solar Radiation, Zenith
Scientific paper
The paper presents an experimental technique which measures j/O3-O(1-D)/, the rate of solar photolysis of ozone to singlet oxygen atoms. It is shown that a flow actinometer carries dilute O3 in N2O into direct sunlight where the O(1D) formed reacts with N2O to form NO which chemiluminescence detects, with a time resolution of about one minute. Measurements indicate a photolysis rate of 1.2 (+ or - .2) x 10 to the -5/s for a cloudless sky, 45 deg zenith angle, 0.345 cm ozone column and zero albedo. Finally, ground level results compare with theoretical calculations based on the UV actinic flux as a function of ozone column and solar zenith angle.
Chameides W. L.
Crutzen Paul J.
Dickerson Russell R.
Fishman Jack
Stedman Donald H.
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