Absorption of light in the atmosphere by collision pairs of oxygen /O2/2

Physics – Optics

Scientific paper

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Absorption Spectra, Atmospheric Optics, Molecular Collisions, Oxygen Spectra, Photoabsorption, Atmospheric Boundary Layer, Nitrogen Dioxide, Optical Paths, Spectral Bands

Scientific paper

Atmospheric absorption bands by collision complexes of oxygen have been measured in long path optical experiments. About 0.0015 of the incoming solar energy is absorbed by the O4 bands in the near UV, visible and near infrared spectral regions. A larger fraction of this energy goes into the 2-km layer above the surface. The possible consequences of excited metastable (O2)2 molecules for atmospheric chemistry are discussed.

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