Absolute state-selected total cross sections for the O(+)(2D,2P) + N2 reactions

Details Absolute state-selected total cross sections for the O(+)(2D,2P) + N2 reactions Absolute state-selected total cross sections for the O(+)(2D,2P) + N2 reactions

Dec 1991

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1991jgr....9621407f&link_type=abstract

Journal of Geophysical Research (ISSN 0148-0227), vol. 96, Dec. 1, 1991, p. 21,407-21,410. Research supported by Petroleum Resea

Physics

7

Charge Transfer, Nitrogen Ions, Nitrogen Oxides, Oxygen Ions, Planetary Atmospheres, Reaction Kinetics, Atmospheric Chemistry, Center Of Mass, Ionic Collisions, Molecular Collisions, Scattering Cross Sections

Scientific paper

Using the triple-quadrupole double-octopole apparatus described by Liao et al. (1986), absolute total cross sections for the reactions O(+)(2D) + N2 or O(+)(2P) + N2 yielding N2(+) + O, NO(+) + N, and N(+) + NO (or N + O) were determined in the center-of-mass collision energy range of 1.3-25 eV. It was found that the charge transfer cross sections were greater for the O(+)(2D) + N2 reaction than for the O(+)(2P) + N2 reaction, in agreement with findings of Lavollee and Henri (1989). The formation of N(+) + NO from O(+)(2D) + N2 was negligible, while that from O(+)(2P) + N2 was finite at collision energy near its threshold.

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