Absolute rates of collisional deactivation of Hg(6p 3P2) by nitrogen and carbon monoxide

Details Absolute rates of collisional deactivation of Hg(6p 3P2) by nitrogen and carbon monoxide Absolute rates of collisional deactivation of Hg(6p 3P2) by nitrogen and carbon monoxide

Dec 1974

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1974jchph..61.5158b&link_type=abstract

Journal of Chemical Physics, Volume 61, Issue 12, pp. 5158-5161 (1974).

Physics

Chemical Physics

8

Scientific paper

The total rates of collisional deactivation of the 6p 3P2 state of mercury by nitrogen and carbon monoxide have been measured. The experimental technique involved the use of a narrow-band cw dye laser to probe the absorption at the center of the 5461 Å line of mercury in an optically pumped cell as a function of the pressure of the deactivating gases. The measured rates at 325°K were 3.0×106 and 6.2×106 sec-1.Torr-1 for deactivation by N2 and CO, respectively. Also measured were the rates of collisional deactivation from the 7s 3S1 level into the 6p 3P2 level. These partial quenching rates were found to be less than 7×105 sec-1.Torr-1 for N2, and equal to 4.4×106 sec-1.Torr-1 for CO.

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