Absolute interaction-induced light scattering spectral intensities from helium diatoms over a large frequency domain

Statistics – Computation

Scientific paper

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Potential Energy Surfaces For Collisions, Electric And Magnetic Moments, Polarizability, And Magnetic Susceptibility, Electric And Magnetic Moments, Polarizability

Scientific paper

Interaction-induced light scattering spectra from gaseous helium are measured up to 740 cm-1 at room temperature and for various densities. From our data, depolarized and isotropic components induced by binary interactions are extracted in absolute units over a large frequency domain unstudied as yet. Comparison of our experimental data is made with results from a quantum-mechanical computation based on a recently proposed numerical procedure. The induced polarizability model proposed by Moszynski and coworkers is found to remarkably reproduce the experimental results, allowing for a deeper comprehension of the atomic dynamics at short internuclear distances.

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