Interatomic potentials of Cd-Kr from far-wing line profiles

Details Interatomic potentials of Cd-Kr from far-wing line profiles Interatomic potentials of Cd-Kr from far-wing line profiles

Apr 1999

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1999aipc..467..444r&link_type=abstract

The 14th international conference on spectral line shapes. AIP Conference Proceedings, Volume 467, pp. 444-448 (1999).

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Potential Energy Surfaces For Collisions, Line Shapes, Widths, And Shifts

Scientific paper

The intercombination absorption line of the Cd (326.1 nm) line broadened by pressure effects of Kr in the spectral range extending from 800 cm-1 in the blue wing to 1200 cm-1 in the red wing was studied using a high resolution spectrometer. The temperature dependence of the studied line was analyzed in the framework of the quasi-static theory. This analysis allowed us to determine the ground (X10+), and the excited (31,30+) state potentials at the internuclear separations from 3.2 Å to 6.3 Å. The well depths with their positions for these states are respectively equal to (134+/-7 cm-1, 3.95+/-0.2 Å), (72.3+/-4 cm-1, 4.95+/-0.3 Å) and (471+/-12 cm-1, 3.6 Å). These values are in close agreement with those obtained for this mixture (Cd-Kr) from other experimental methods.

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