Physics – Optics
Scientific paper
Dec 1983
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1983apopt..22.3805r&link_type=abstract
Applied Optics (ISSN 0003-6935), vol. 22, Dec. 1, 1983, p. 3805-3809. NASA-supported research.
Physics
Optics
37
Carbon Dioxide, Infrared Spectra, Spectral Bands, Spectrum Analysis, Vibrational Spectra, Coriolis Effect, Least Squares Method, Molecular Rotation, Spectral Line Width
Scientific paper
A nonlinear least-squares fitting procedure has been used to derive absolute intensities for lines in the P, R, and Q branches of the (11/1/0)II-00/0/0 band of (C-12)(O-16)2 (band center = 1932/cm) from long-path 0.01/cm resolution laboratory spectra. The spectral data were recorded at room temperature and low pressure (less than 10 torr) with the Fourier transform spectrometer in the McMath solar telescope complex at Kitt Peak National Observatory. The observed line intensities were analyzed to derive the vibrational band intensity and F-factor coefficients. To obtain a good fit to the data, it was necessary to include terms in the expression for the F factor, which account for Coriolis-type and Fermi-type interactions and centrifugal distortion effects.
Benner Chris D.
Richardson John D.
Rinsland Curtis P.
Toth Robert A.
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