A Symmetry Adapted Approach to Molecular Spectroscopy: The Anharmonic Oscillator Symmetry Model

Details A Symmetry Adapted Approach to Molecular Spectroscopy: The Anharmonic Oscillator Symmetry Model A Symmetry Adapted Approach to Molecular Spectroscopy: The Anharmonic Oscillator Symmetry Model

1996-03-13

arxiv.org/abs/chem-ph/9603002v1

Rev. Mex. Fis. 42, Suplemento 1 (1996) 73

Physics

Chemical Physics

12 pages, invited talk at XIX Oaxtepec Symposium on Nuclear Physics, January 1996

Scientific paper

We apply the Anharmonic Oscillator Symmetry Model to the description of vibrational excitations in ${\cal D}_{3h}$ and ${\cal T}_d$ molecules. A systematic procedure can be used to establish the relation between the algebraic and configuration space formulations, by means of which new interactions are found in the algebraic model, leading to reliable spectroscopic predictions. We illustrate the method for the case of ${\cal D}_{3h}$-triatomic molecules and the ${\cal T}_d$ Be-cluster.

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