A study of pre-sunrise changes in the negative ions and electrons in the D-region

Physics

Scientific paper

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D Region, Ionospheric Electron Density, Negative Ions, Height, Hydrogen Atoms, Oxygen Atoms, Ozone, Pair Production, Photodissociation, Photoionization, Solar Radiation

Scientific paper

A negative-ion model, based on gas-phase reactions, is used to study the detachment processes responsible for increases of electron concentrations observed in the lower D-region between nighttime and ground sunrise, before the arrival of ionizing solar radiations. The height distributions of negative-ion species, electrons, and total positive ions are obtained from time-dependent solutions of the corresponding continuity equations which incorporate simultaneous solutions for the minor neutral constituents involved. These distributions are used to identify the roles of chemical reactions involving minor neutral constituents, photodissociation, and photodetachment processes for negative ions in determining the observed presunrise changes in electron concentrations. It is shown that processes involving CO3(-) ions control the onset of the pre-sunrise changes but that NO3(-) ions must be involved in the electron concentration increases observed below about 75 km nearer ground sunrise.

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